3-(Diphenylchalcogenophosphoryl)propionic acids as precursors for metal selenides and tellurides

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Authors

KUBÁT Václav BABIAK Michal TRÁVNÍČEK Zdeněk NOVOSAD Josef

Year of publication 2017
Type Article in Periodical
Magazine / Source Polyhedron
MU Faculty or unit

Faculty of Science

Citation
Doi http://dx.doi.org/10.1016/j.poly.2016.12.034
Field Inorganic chemistry
Keywords 3-(Diphenylphosphino)propionic acid; Cadmium selenide; Mercury chalcogenide; Lead chalcogenide; Synthesis
Description New reaction systems leading to cadmium, mercury and lead selenides and tellurides are reported. The chalcogenides were prepared by a simple, direct reaction between chalcogen, metal oxide or carbonate, and 3-(diphenylphosphino)propionic acid. The synthesis of 3-(diphenyltellurophosphoryl)propionic acid (1) is described and X-ray structures of 3-(diphenylphosphino)propionic acid (2) and its P=E derivatives are presented, where E = O (3), S (4) and Se (5).
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